A Kinetic Model Based on the Sequential Reaction Mechanism for the Noncatalytic Reformation of Jet Fuel in Supercritical Water

Jonathan Wenzel; J. Picou; A. Niemoeller; Sunggyu Lee; H.B. Lanterman

doi:10.1080/15567030903261899

A Kinetic Model Based on the Sequential Reaction Mechanism for the Noncatalytic Reformation of Jet Fuel in Supercritical Water

Jonathan Wenzel, J. Picou, A. Niemoeller, Sunggyu Lee, H.B. Lanterman

Kettering University

Research output: Contribution to journal › Article › peer-review

Abstract

An experimental kinetic study was performed on the supercritical water reformation of jet fuel to account for the interactive contributions of three principal reactions that are taking place, viz., non-catalytic reformation of original and fragmented hydrocarbon molecules, pyrolysis of hydrocarbon molecules, and water gas shift reaction. Experiments were conducted non-catalytically using supercritical water and jet fuel in a specially designed 926 mL Inconel 625 Grade-1 tubular reactor at temperatures varying from 803 to 972 K at a pressure of 24.15 ± 0.06 MPa. The Arrhenius activation energies and frequency factors were obtained for each of the three principal reactions.

Original language	American English
Journal	Energy Sources: Part A
Volume	33
DOIs	https://doi.org/10.1080/15567030903261899
State	Published - Feb 18 2011

Keywords

Kinetic
Supercritical Water
Reformation
Jet Fuel
Hydrocarbon

Disciplines

Engineering
Physical Sciences and Mathematics

Access to Document

10.1080/15567030903261899License: Unspecified

Cite this

@article{675c6c66f31a421d8e66df1a3f75a1ee,

title = "A Kinetic Model Based on the Sequential Reaction Mechanism for the Noncatalytic Reformation of Jet Fuel in Supercritical Water",

abstract = " An experimental kinetic study was performed on the supercritical water reformation of jet fuel to account for the interactive contributions of three principal reactions that are taking place, viz., non-catalytic reformation of original and fragmented hydrocarbon molecules, pyrolysis of hydrocarbon molecules, and water gas shift reaction. Experiments were conducted non-catalytically using supercritical water and jet fuel in a specially designed 926 mL Inconel 625 Grade-1 tubular reactor at temperatures varying from 803 to 972 K at a pressure of 24.15 ± 0.06 MPa. The Arrhenius activation energies and frequency factors were obtained for each of the three principal reactions.",

keywords = "Kinetic, Supercritical Water, Reformation, Jet Fuel, Hydrocarbon",

author = "Jonathan Wenzel and J. Picou and A. Niemoeller and Sunggyu Lee and H.B. Lanterman",

note = "An experimental kinetic study was performed on the supercritical water reformation of jet fuel to account for the interactive contributions of three principal reactions that are taking place, viz., non-catalytic reformation of original and fragmented hydrocarbon molecules, pyrolysis of hydrocarbon molecules, and water gas shift reaction.",

year = "2011",

month = feb,

day = "18",

doi = "10.1080/15567030903261899",

language = "American English",

volume = "33",

journal = "Energy Sources: Part A",

}

TY - JOUR

T1 - A Kinetic Model Based on the Sequential Reaction Mechanism for the Noncatalytic Reformation of Jet Fuel in Supercritical Water

AU - Wenzel, Jonathan

AU - Picou, J.

AU - Niemoeller, A.

AU - Lee, Sunggyu

AU - Lanterman, H.B.

N1 - An experimental kinetic study was performed on the supercritical water reformation of jet fuel to account for the interactive contributions of three principal reactions that are taking place, viz., non-catalytic reformation of original and fragmented hydrocarbon molecules, pyrolysis of hydrocarbon molecules, and water gas shift reaction.

PY - 2011/2/18

Y1 - 2011/2/18

N2 - An experimental kinetic study was performed on the supercritical water reformation of jet fuel to account for the interactive contributions of three principal reactions that are taking place, viz., non-catalytic reformation of original and fragmented hydrocarbon molecules, pyrolysis of hydrocarbon molecules, and water gas shift reaction. Experiments were conducted non-catalytically using supercritical water and jet fuel in a specially designed 926 mL Inconel 625 Grade-1 tubular reactor at temperatures varying from 803 to 972 K at a pressure of 24.15 ± 0.06 MPa. The Arrhenius activation energies and frequency factors were obtained for each of the three principal reactions.

AB - An experimental kinetic study was performed on the supercritical water reformation of jet fuel to account for the interactive contributions of three principal reactions that are taking place, viz., non-catalytic reformation of original and fragmented hydrocarbon molecules, pyrolysis of hydrocarbon molecules, and water gas shift reaction. Experiments were conducted non-catalytically using supercritical water and jet fuel in a specially designed 926 mL Inconel 625 Grade-1 tubular reactor at temperatures varying from 803 to 972 K at a pressure of 24.15 ± 0.06 MPa. The Arrhenius activation energies and frequency factors were obtained for each of the three principal reactions.

KW - Kinetic

KW - Supercritical Water

KW - Reformation

KW - Jet Fuel

KW - Hydrocarbon

UR - https://www.tandfonline.com/doi/full/10.1080/15567030903261899?scroll=topneedAccess=true

U2 - 10.1080/15567030903261899

DO - 10.1080/15567030903261899

M3 - Article

VL - 33

JO - Energy Sources: Part A

JF - Energy Sources: Part A

ER -

A Kinetic Model Based on the Sequential Reaction Mechanism for the Noncatalytic Reformation of Jet Fuel in Supercritical Water

Abstract

Keywords

Disciplines

Access to Document

Other files and links

Cite this